Dimethylcobalt(Ⅲ) complexes containing salicylaldiminato(N:O) and trimethylphosphine ligands
更新时间:2019-05-21
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作者联系方式:山东大学化学与化工学院;
会议名称:中国化学会第十三届金属有机化学学术讨论会
会议地点:中国北京
召开年:2004
出版社:中国化学会
摘要:CoL3Me3(L=PMe3) reacts with phenol, salicylaldehyde, and β-keto-aldehyde to give cis-dimethyl-cobalt(Ⅲ) complexes. We have introduced the isoelectronic salicylalimihe Schiff base ligands under similar conditions and report here the synthesis of a series of 6-coodinate cis-dimethyl-trans-bis(trimethylphosphine) salicylaldiminato cobalt(Ⅲ) compounds.